Environmental chemistry notes: what is the structure of atmosphere and explain zones of the atmosphere?

The atmosphere is a protective covering around us and broadly segmented into different zones. Each zone possesses specific characteristics and composition. On the basis of temperature atmosphere is divided into four major zones. The ascending order of these temperature zones of atmosphere with respect to distance from earth is given as follows

1.      Troposphere

2.      Stratosphere

3.      Mesosphere

4.      Thermosphere

1. Troposphere:

This region of atmosphere lies nearest to the surface of the earth and possesses about 70% of the total mass of atmosphere. This the region of the atmosphere where life exists thus included in biosphere. The characteristics of this zone are discussed one by one

a)      Distance from earth’s surface

It starts from the surface of the earth in form of gaseous phase and extends upto 11 km high from the surface of the earth. To illustrate it further, it ranges from 0-11 km from the surface of the earth.

b)     Composition

Fundamental chemical species in this region are oxygen (O2), carbon dioxide (CO2), nitrogen (N2) and water vapors (H2O). Water vapors mostly evaporate from the surface thus usually present in the lower region of this zone. It contains about 99% of the total water vapors of atmosphere. Constant flow of air mix up these vapors with different gasses randomly.

c)      Lapse rate

Laps rate can be defined as change in temperature with respect to increase in altitude. The range of temperature in troposphere is -56-15oC. Troposphere shows a negative lapse rate as temperature shows a uniform decrease with increasing the altitude. At sea level temperature of this zone is 15oC which decreases upto -56oC at the height of 11 km above the sea level.

d)     Tropopause

Tropopause is a cold layer at the boundary of this zone and stratosphere where temperature inversion occurs. This is also called transition layer of troposphere above which temperature changes dramatically as the next zone of troposphere starts.   

e)      Residence time of particles

Air is not uniform in this zone and most of weather depends on conditions of troposphere. Non uniformity of air and constant flow of air does not allow the molecules or pollutants to reside for a long time in air.

f)       Density

Density of troposphere is directly proportional to the altitude and it shows an exponential decrease with increasing the altitude.

2. Stratosphere:

This is the second zone of atmosphere which lies immediately above the troposphere. The main characteristics of this zone are given as follows

a)      Distance from earth’s surface

Stratosphere starts at the height above 11 km from the surface of the earth and extends upto 50 km. It ranges from 11 km 50 km above the earth’s surface.

b)     Composition

Stratosphere contains ozone layer (O3) which serves as a protective shield from the hostile outer space.

c)      Lapse rate

Stratosphere possesses a positive lapse rate and is also named as quiescent layer as it shows an increasing trend in temperature with increase in altitude. Temperature in this region increases from -56oC at 11 km to -2oC at 50 km. The main contributing factor of increasing temperature in the region is that ozone layer absorbs ultraviolet radiations.

d)     Stratopause

This is the transition layer between stratosphere and the next region of the atmosphere named mesosphere. At stratosphere temperature inversion occurs among two zones.    

e)      Residence time of particles     

The residence time of pollutants and molecules is long in this region due to slow mixing mechanism in stratosphere. The clouds do not mix up with air in this region thus the air is usually dry. The hazardous effects of pollutants in stratosphere are more drastic as compared to troposphere due to prolong residence time.

3. Mesosphere:

This is the third zone of the atmosphere lies immediately above the stratosphere. Characteristic features of mesosphere are discussed as follows

a)      Distance from earth’s surface

This region starts from 50 km above the earth’s surface and extends upto 85 km. this zone ranges from 50 to 80 km.

b)     Composition:

Chemical constituents of this region are O2+ and NO+.

c)      Lapse rate:

Mesosphere possesses a negative lapse rate as the temperature in this zone decreases with increase in height. The average temperature of the mesosphere decreases from -2oC at 50 km height from surface of the earth to -96oC at a height of 85 km from the earth’s surface. Minute amount of ozone and other ultraviolet absorbing species are basically responsible for the temperature inversion in this region.

d)     Mesopause

This is the transition layer between mesosphere and thermosphere where lapse rate changes from negative in mesosphere to positive in thermosphere.

4. Thermosphere:

This is the fourth and last zone of atmosphere which lies above the mesosphere and separated from mesosphere via mesopause. The characteristics of this zone are discussed as follows

a)      Distance from earth’s surface

This zone of atmosphere starts from the height of 85 km above the surface of the earth and extends upto 500 km. the range of thermosphere is from 85-500 km from earth’s surface.

b)     Composition

Positive ions including O2+, O+ and NO+ are the main chemical species of thermosphere.

c)      Lapse rate

Thermosphere possesses a positive lapse rate as temperature in this zone increases uniformly with increase in temperature. The temperature in thermosphere at the height of 85 km immediately above the mesopause is -92oC which rises upto 1200oC at the height of 500 km. Solar radiations in this region are being absorbed by oxygen and nitric oxide gasses which give rise to ionization responsible for the increase in temperature in this region. The lower region in this zone is specifically called as ionosphere due the presence of ionic species. The air in the upper region of this zone is quite less dense with respect to chemical species.

Figure 1 shows the various components of the atmosphere possessing different lapse rate.



Figure. 1. Different zones of atmosphere having divergent lapse rate

  

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