Fundamental concepts in chemistry: Define x-rays and Moseley’s law

X-rays are fundamentally electromagnetic radiations which produced when fast moving electrons strike with a metal anode in a discharge tube. When these striking electrons stop at once on collision with a metal anode the released energy is in the form of electromagnetic waves.

In a detailed procedure the electrons are first produced in the discharge tube by heating the tungsten filament. These electrons are then accelerated through high voltage which provides these electrons sufficient energy to emit x-rays on striking the metal target. The wavelength of the emitting x-rays solely depends upon the nature of metal selected as target anode.

Henry G. J. Moseley worked a lot of experiments on x-rays and used different metals as target anode ranging from Al to gold. He also discovered x-rays spectrum and explain some fundamental concepts about x-rays given as follows.

1. The spectral lines obtained through x-rays can be divided into two different groups depending upon the wavelength.

            (i). K series

                        The spectral lines of x-rays falling in K series possess shorter wavelength.

            (ii). L series

                        The spectral lines of x-rays in L series have longer wavelength.

2. The of produced x-rays is highly dependent upon the atomic number of target metal. If the target metal is of higher atomic number, the wavelength of x-rays produced will be shorter and vice versa.

3. Moseley’s law:

This law states that ‘The square root of frequency of a spectral line in x-rays varies directly with the change in atomic number of the target metal producing the x-rays spectrum”.

Where

Z = atomic number of target metal

While a & b are constants

Thus according to equation 1 the frequency of the x-rays produced solely depends upon the atomic number of the target metal. 


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